WebABSTRACT: The photodissociation of jet-cooled cyclohexyl was studied by exciting the radicals to their 3p Rydberg state by using 248 nm laser light and detecting photoproducts by photofragment translational spectroscopy. Both H atom loss and dissociation to heavy fragment pairs are observed. WebApr 13, 2024 · A series of complexes of Na, K, NH4, and H3O with [bpy.bpy.bpy]cryptand, [2.2.2]cryptand, and spherical cryptand were investigated via DFT and ab initio methods. We found that by coating Rydberg molecules with the “organic skin” one could further decrease their ionization potential energy, reaching the values of ∼1.5 eV and a new low record of …
Rydberg Definition & Meaning Dictionary.com
WebAug 21, 2014 · The electron is an efficient catalyst for conducting various types of radical cascade reaction that proceed by way of radical and radical ion intermediates. But because electrons are omnipresent ... WebThis Perspective overviews two roles that Rydberg radicals can play, both of which have important chemical consequences. Attachment of an electron into excited Rydberg … je cute
Electronic transitions in the Rydberg radical H3O
WebThis Perspective overviews two roles that Rydberg radicals can play, both of which have important chemical consequences. Attachment of an electron into excited Rydberg … WebThe Oxonium Rydberg Radical: Electronic Transitions C. Lavin and I. Martin Departamento de Quimica Fisica Facubd de Ciencias; Universidad de VaUadolid 47005 VaUadolid, Spain … Weba vibronically resolved Rydberg state, and therefore Rydberg-valence interaction must influence the subsequent dynamics. Second, there is more than one pathway that can terminate in D photofragments. Third, the role of isomerization to the methoxy radical can be investigated by comparing the H and D signals obtained in the photolysis of CD2OH ... jecv